Hi Dylan,
The only thing that qualifies me in attempting to help you is that I have had many a head scratching session over electrical anomalies in classic Audi 80 Cabriolets.
is there any noise coming from the rear left window? If there is it is possibly a broken steel cable or pulley in the windows mechanism, If you can’t hear a motor running then it could be the actual motor, a relay or a broken cable, it may also be the switch in the driver’s door. The windows master switch only operates in one direction, I think this could be the switch or one of the master switch relays, as far as I’m aware there is a master down relay and a master up relay. The first step would be to test the switch, then the relay, then the wiring. Sorry I can’t be more definitive, I’ve attached two diagrams that may be of some help.
Turlough.